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The mash is the first enzymatic process in the brewing day, where the germination enzymes in the barleycorn are reactivated. By steeping the kilned malt in warm water, the enzymes that were paused during malting are brought back to life for use in the brewhouse. This step is crucial for converting the grain’s starches into fermentable sugars.
The main purpose of mashing is to continue the germination process and break down the complex starches stored in the barley. Amylase enzymes work to divide these starches into simpler sugar chains, which yeast can easily consume during fermentation, leading to alcohol production.
During the mash, several key enzymes convert the starches and proteins in the grain into fermentable sugars and other essential components. The most important enzymes are β-amylase, α-amylase, and protease.
β-amylase: This enzyme breaks down starches at the ends of the chains, primarily producing maltose, a fermentable sugar. β-amylase works best at lower temperatures and requires more time, leaving behind larger dextrins when breaking down amylopectin.
α-amylase: This enzyme cleaves starches in the middle of their chains, allowing β-amylase to create more maltose. α-amylase works at higher temperatures and is more heat-tolerant, converting both amylose and amylopectin into smaller sugar chains and dextrins.
Protease (Proteinase): Protease enzymes are responsible for breaking down large proteins into smaller peptides and amino acids, which are essential for yeast nutrition and help improve head retention and beer clarity. These enzymes work best at lower temperatures, often during the protein rest stage of mashing.
By carefully controlling the mash temperature, brewers can manipulate enzyme activity to balance the breakdown of starches and proteins, which directly affects the beer’s body, flavor, and fermentability.
Table 1 - Main Groups of Mashing Enzymes
Mashing is the initial step in the brewing process where crushed grains are mixed with water, creating a porridge-like substance called the mash. During mashing, the starches and proteins in the grain are broken down into simpler components like sugars and amino acids, producing the sweet liquid known as wort. The goal of mashing is to convert the long-chain starches in the grain into fermentable sugars, which yeast will later turn into alcohol during fermentation.
Malt, which arrives at the brewery in whole kernels, is first milled into a coarse powder called grist. The grist is then combined with a precisely measured amount of warm or hot water. The choice of mashing method—infusion mashing, decoction mashing, or temperature-controlled infusion mashing—depends on the brewery's equipment, the malt quality, and the style of beer being brewed. These methods help ensure that the starches in the grain break down into fermentable sugars. Mash temperature control is critical to activating the necessary enzymes that make this conversion possible.
When setting up your mash, one of the most critical factors to consider is the mash temperature. The ideal temperature will ensure that starches in the malt liquefy or dissolve at the right setpoint, allowing for proper enzyme activity. For an all-malt grist made from barley, the starch liquefaction temperatures often overlap with starch conversion temperatures. However, for grains like rice and corn, liquefaction occurs at higher temperatures, so they require a separate cereal mash or need to be used as flaked grains.
Figure 1 - Starch Liquification Temperatures (Briggs, et al., 2004)
Most mashes rest between 63°C and 69°C (145°F to 156°F), where different enzymes operate at different efficiency levels:
Lower mash temperatures favor β-amylase, which produces a more fermentable wort, leading to a lighter body and drier finish. This is ideal for styles like pilsners or session beers.
Higher mash temperatures favor α-amylase, which creates more dextrins, resulting in a fuller body and residual sweetness. This is better suited for richer beer styles like stouts or barleywines.
Choosing the right mash temperature helps brewers achieve the desired body in the final beer. For lower starting gravity beers, a moderate to high mash temperature works well due to the small grain bills. On the other hand, table strength beers benefit from lower mash temperatures, while imperial strength beers should also aim for lower temperatures to maintain a balanced sugar content.
The final sugar levels directly affect the beer’s balance, influencing the interplay of flavors from hops, alcohol, and overall drinkability. Lower mash temperatures result in a lighter body, a drier mouthfeel, and a milder flavor.
The single infusion mash is the simplest and most common method of mashing, especially in modern breweries. In this method, the grist (crushed grain) is mixed with hot water to reach the desired mash temperature. To account for the cooler grain, the strike water—the water added to the grain—is usually heated above the target mash temperature. Once mixed, the mash should remain at a consistent temperature, so the mash tun needs to be insulated or equipped with an external heat source.
This method is best suited for well-modified malts, as it allows for steady and easy temperature control by adjusting the water. Brewers can add either hot or cold water to adjust the mash temperature if needed. Single infusion mashing is particularly efficient for pale ales and lagers, where highly modified malt and simpler recipes are commonly used.
In a multi-step mash, the mash undergoes several temperature rests, allowing for different enzyme activities at each stage. This process starts by heating the strike water to bring the mash to an initial rest temperature, like the protein rest. After each rest, the temperature is raised either by adding hot water or using an external heat source. It is crucial to mix the mash thoroughly with a mash paddle or mechanical agitator to ensure consistent temperatures throughout.
Multi-step mashes are especially useful for recipes that include unmalted grains, such as wheat or corn, which need more precise temperature control to liquefy starches and convert them effectively. This method provides the brewer with greater control over the final wort composition but is more labor-intensive, particularly when using traditional mash/lauter tuns.
The decoction mash was developed to address the limitations of older malting techniques, where malts were less modified. In this method, a portion of the mash is removed and boiled in a separate vessel, destroying the enzymes but generating complex malt flavors through Maillard reactions. The boiled portion is then returned to the mash tun, which raises the overall temperature of the mash.
Though decoction mashing was once the standard, modern malting advancements have made it less common today. However, it is still used in traditional brewing styles, particularly in German lagers, where the complex malt character is highly valued. Many brewers continue to swear by the results, claiming that decoction mashing brings out rich, caramelized malt flavors that can’t be replicated with other mashing methods.
Missing the correct mash temperature can lead to significant issues with your wort. If the mash temperature is too low, you risk incomplete starch conversion, resulting in a wort that lacks fermentable sugars. This means the yeast will not have enough sugar to ferment into alcohol, leading to poor fermentation and low alcohol levels. On the other hand, if the temperature is too high, you could end up with a wort that contains too many unfermentable sugars, resulting in a sweeter, fuller-bodied beer than intended.
To avoid these issues, using a strike temperature calculator is highly recommended. This tool helps dial in the correct water temperature for your mash, ensuring consistent and reliable conversion of starches into fermentable sugars.
When the mash is too cold, it’s essential to add heat to ensure proper starch liquefaction and enzyme activity. Here are some ways to raise the mash temperature:
Add additional hot water: This method is quick and easy but can dilute the mash, affecting the concentration of enzymes and reducing the efficiency of the conversion process. It’s also important to ensure that the mash tun has enough space for the added water.
Direct heating: Using an element, burner, or steam to heat the mash tun can be effective, especially for smaller systems. However, heating lauter tuns is difficult due to the presence of runoff ports and potential scorching. Additionally, lauter rakes can interfere with accurate temperature sensors.
Decoction mashing: This method involves removing a portion of the mash, heating it to the conversion temperature, and boiling it before returning it to the main mash. Decoction mashing raises the temperature without adding extra water and also increases extraction efficiency, especially with continental malts. It enhances flavor through Maillard reactions and is often used for traditional styles like Munich lagers.
If the mash temperature is too high, you’ll need to cool it down quickly to avoid producing too many unfermentable sugars. Here are some effective methods:
Add additional cold water: Adding cold water can rapidly lower the mash temperature. Vigorous stirring helps distribute the cooler water evenly, preventing localized overheating. This method avoids the risk of tannin extraction, but be sure the water used is free from chlorine and at the correct mineral content.
Use a heat exchanger: For larger systems, a heat exchanger connected to cooling water or glycol can quickly bring down the mash temperature. Nano systems may use an immersion chiller, while larger setups can use a shell and tube or plate and frame heat exchanger. However, be cautious not to cool the wort too quickly, as this can cause pumping issues due to increased viscosity. It’s also important not to overcorrect, as reheating the mash after adding too much water can be challenging.
The most common method for checking if mashing is complete is the iodine test, which detects any unconverted starches in the mash. This simple test is a reliable way for brewers to ensure that the enzymes have broken down the starches into fermentable sugars.
If starches are present, the iodine will turn black, indicating incomplete starch conversion. If the conversion is complete, the iodine will remain a light brown color, confirming that the starches have been fully broken down into fermentable sugars.
The iodine test is a quick and effective way to determine mash completion. However, it can be trickier to use with turbid mashing methods, such as those used in Lambic brewing or grain-based distilleries, due to the cloudiness of the wort.
Temperature control is crucial for ensuring proper mashing and enzyme activity, especially in larger-scale brewing operations. When relying solely on a mash tun for starch conversion, maintaining precise temperatures or correcting strike water temperatures can become difficult as the brewing scale increases. For craft breweries that grow beyond a certain size, manual mashing becomes impractical, requiring the use of rakes and plough systems to mix the mash efficiently.
Additionally, using a standard lauter tun to control mash temperature presents challenges. The rakes' temperature sensors can easily become damaged, and heating jackets can scorch the mash beneath the false bottom, leading to uneven heating and compromised beer quality.
For breweries producing 20bbl and up, a mash mixer is highly recommended. Mash mixers offer brewers precise control over mash temperatures, making it easier to adjust or fix incorrect strike water temperatures. They also provide more flexibility in setting multi-step mash profiles, improving mash efficiency and conversion rates.
Another key advantage is that mash mixers allow for faster turnover in the lauter tun, enabling breweries to complete more brews in a single day. This level of control and efficiency enhances beer consistency and quality, resulting in superior-tasting beers that meet production goals.
Maintaining control over mash temperature is essential to ensuring successful starch conversion and creating the desired body, flavor, and mouthfeel in your beer. From understanding the activity of enzymes like β-amylase and α-amylase to selecting the right mashing method—whether it’s single infusion, multi-step, or decoction mashing—temperature precision plays a key role at every stage of the mash process.
Missing your mash temperature can lead to incomplete conversions, unfermentable sugars, or stuck lauters, so having a plan for temperature corrections, whether through additional water or the use of decoction mashing, is crucial. Simple tools like the iodine test help ensure mash completion, giving brewers confidence that the starches have been fully converted to sugars.
For larger breweries, a mash mixer becomes an invaluable tool, providing more precise control over mash profiles and enabling efficient multi-step mashing. This leads to better brewhouse efficiency, consistent results, and higher-quality beers, allowing breweries to meet production demands while maintaining flavor and consistency.
By understanding and mastering mash temperature control, brewers can enhance their brewing process, improve efficiency, and, most importantly, produce consistently great beer.
Briggs, D. E., Brookes, P. A., Stevens, R. & Boulton, C. A., 2004. Brewing: Science & Practice. Cambridge: Elsevier Science & Technology.
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